chemical solution

Chemistry

2022

We explain what a chemical solution is and its main characteristics. Also, how is it classified and what is concentration.

A chemical solution is a homogeneous mixture of two or more substances.

What is a chemical solution?

A chemical solution or solution is called a homogeneous mixture of two or more pure chemicals. A dissolution can occur at the molecular or ionic level and does not constitute a chemical reaction.

In this way, the solution resulting from the mixture of two components will have a single recognizable phase (solid, liquid or soda) even though its separate components had different phases. For example, when dissolving sugar in Water.

Every chemical solution has at least two components: a solute (which is dissolved in the other) and a solvent or solvent (which dissolves the solute). In the case of sugar dissolved in water, sugar is the solute and water is the solvent.

The formation of solutions and mixture s of substances is essential for the development of new materials and for understanding the chemical forces that allow matter to combine. This is of particular interest to the fields of chemistry, the biology and geochemistry, among others.

Characteristics of a chemical solution

In a chemical solution its elements cannot be distinguished with the naked eye.

In general, any chemical solution is characterized by:

  • Solute and solvent cannot be separated by physical methods such as filtration or sifted, since their particles they have constituted new chemical interactions.
  • They have a solute and a solvent (at a minimum) in some detectable proportion.
  • Its constituent elements cannot be distinguished with the naked eye.
  • Only solute and solvent can be separated by methods such as distillation, the crystallization wave chromatography.

Types of chemical solution

Chemical solutions can be classified according to two criteria.

The ratio of solute to solvent:

  • Diluted. When the amount of solute with respect to the solvent is very small. For example: 1 gram of sugar in 100 grams of water.
  • Concentrated. When the amount of solute with respect to the solvent is large. For example: 25 grams of sugar in 100 grams of water.
  • Saturated. When the solvent no longer accepts any more solute at a certain temperature. For example: 36 grams of sugar in 100 grams of water at 20 ° C.
  • Oversaturated Since saturation has to do with temperature, if we increase the temperature, we can force the solvent to take in more solute than it ordinarily can, obtaining a supersaturated solution (over-saturated, let's say). Thus, subjected to heating, the solution will take up much more solute than it ordinarily could.

The aggregation status of the components:

Solid:

  • Solid on solid.Both the solute and the solvent are in the solid state. For example: alloys like brasscopper and zinc).
  • Solid gas. The solute is a gas and the solvent is a solid. For example: hydrogen in palladium, volcanic dust, among others.
  • Liquid in solid. The solute is a liquid and the solvent is a solid. For example: amalgams (mercury and silver)

Liquids:

  • Solid in liquid. Generally, small amounts of solid (solute) are dissolved in a liquid (solvent). For example: sugar dissolved in water.
  • Gas in liquid. A gas (solute) is dissolved in a liquid (solvent). For example: dissolved oxygen in water from sea which is responsible for aquatic life on the planet.
  • Liquid in liquid. Both solute and solvent are liquid. For example: amalgams (mercury and silver)

Sodas:

  • Gas into gas. Both solute and solvent are gases. On many occasions these solutions are assumed to be mixtures due to the weak interactions between the gas particles. For example: oxygen in air.
  • Solid gas. The solute is a gas and the solvent is a solid. For example: dust dissolved in air.
  • Liquid in gas. The solute is a liquid and the solvent is a gas. For example: water steam in the air.

Concentration of a chemical solution

Concentration is a quantity that describes the proportion of solute relative to the solvent in a solution. This magnitude is expressed in two different types of units:

Physical units. Those that are expressed in relation to weight and to volume of the solution, as a percentage (multiply by 100). For example:

  • % Weight / weight. It is expressed in grams of solute over grams of solution.
  • % Volume / volume. It is expressed in cubic centimeters (cc) of solute over cc of solution.
  • % Weight / volume. Combine the previous two: grams of solute over cc of solution.

Chemical units. Those that are expressed in systems of chemical units. For example:

  • Molarity (M). It is expressed in number of moles of solute over one liter of solution or one kilogram of solution. It is calculated as follows:

Where n (X) is the number of moles of component X and Dissolution is the volume of the solution. Molarity is expressed in moles / L solution.

  • Molar fraction (Xi). It is expressed in terms of moles of a component (solvent or solute) in relation to the total moles of the solution, as follows:

Xsolution = moles of solute / (moles of solute + moles of solvent)

Xsolvent = moles of solvent / (moles of solute + moles of solvent)

Always contemplating that:

Xsolvent + Xsolution = 1

The mole fraction is dimensionless, that is, it is not expressed in units of measurement.

  • Molality (m). It is the ratio between the number of moles of any dissolved solute per kilograms of solvent. It is calculated as follows:

Where m (X) is the molality of X, n (X) is the number of moles of X and mass (solvent) is the mass of solvent expressed in kg. It is important to clarify that molarity is expressed per kg (1000g) of solvent. It is expressed in units of mol / kg.

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